Much of Caracas is eerily empty for a working day. Some in the opposition called for a strike but many people are simply staying at home out of uncertainty, too concerned about what the new currency will mean for the embattled nation to venture out.
The result is that Venezuela is, in essence, a paralysed country. Confusion reigns in the oil-rich nation and, historically, such moments in Venezuela can be extremely volatile.
As yet, there are no reports of significant protests or violence, but there is an increased deployment of the security forces across the country for the roll out of the new bolivar.
President Nicolas Maduro has said the measure will be the saviour of the economy and tackle the spiralling hyper-inflation. Ordinary people however, simply don't believe him and are concerned for the future, putting even greater pressure on neighbouring countries struggling to deal with the exodus of millions of Venezuelans.
The new currency lops five zeroes off the old "strong bolivar" - meaning a cup of coffee worth 2.5m strong bolivars in the capital Caracas last month now costs 25 sovereign bolivars.
However, people in Caracas told the BBC they were restricted to withdrawing only 10 sovereign bolivars on Tuesday from cash machines.
The country's black market in dollars is even frozen by the currency shift, as confusion reigns.
The government announced several other key economic changes to accompany the new notes, including raising the minimum wage by 34 times its previous level from 1 September, raising VAT and cutting generous fuel subsidies.
President Maduro also said the sovereign bolivar would be tied to the petro, a virtual currency the government says is linked to Venezuela's oil reserves.
But the US has banned its citizens from trading in it, and one cryptocurrency site, ICOindex.com, has even labelled the petro "a scam".
"Anchoring the bolivar to the petro is anchoring it to nothing," economist Luis Vicente León told AFP news agency.